Consortional assoc.: Consortional main: M-ERA.NET-WaterSafe: Sustainable autonomous system for nitrites/nitrates and heavy metals monitoring of natural water sources  Page description

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Details of project

 
Identifier
117849
Type NN
Principal investigator Vonderviszt, Ferenc
Title in Hungarian Konzorcium, társ p.: Consortional main: M-ERA.NET-WaterSafe: Sustainable autonomous system for nitrites/nitrates and heavy metals monitoring of natural water sources
Title in English Consortional assoc.: Consortional main: M-ERA.NET-WaterSafe: Sustainable autonomous system for nitrites/nitrates and heavy metals monitoring of natural water sources
Keywords in Hungarian bioszenzorika
Keywords in English biosensing
Discipline
Organic, Biomolecular, and Pharmaceutical Chemistry (Council of Physical Sciences)70 %
Biophysics (e.g. transport mechanisms, bioenergetics, fluorescence) (Council of Medical and Biological Sciences)30 %
Ortelius classification: Molecular biophysics
Panel Physics 1
Department or equivalent Bio-Nanosystems Laboratory (University of Pannonia)
Participants Jankovics, Hajnalka
Kakasi, Balázs
Starting date 2016-01-01
Closing date 2019-08-31
Funding (in million HUF) 17.325
FTE (full time equivalent) 2.07
state closed project
Summary in Hungarian
A kutatás összefoglalója, célkitűzései szakemberek számára
Itt írja le a kutatás fő célkitűzéseit a témában jártas szakember számára.

The target is a new energy autonomous system based on micro (photo)electrochemical sensors, for concentration measurement of different ionic species in natural water sources.
It focuses on 3 directions: 1) new materials with high efficiency in solar energy harvesting and fabrication of small ultra-thin solar cells together; 2) new microsensors and materials for detection of nitrites/ nitrates and heavy metals in water; 3) low cost autonomous energy system integration and fabrication.
The microsensors for nitrates/nitrites and heavy metals will be of (photo)electrochemical type. A biosensor based on sensing protein molecules, flagellar filaments with specificity to heavy metals will be integrated.
The studied materials will be SnO2, TiO2 and ZnO. The thin films will be prepared by a broad variety of deposition techniques (sol-gel, spray pyrolysis, magnetron sputtering, hydrothermal synthesis) and will have different morphologies (nanowires, nanotubes, spheres) allowing to select the best sensitivity and selectivity for the sensor. Bacterial flagellar filaments (special protein molecules) will be investigated and engineered as sensitive biolayer for heavy metal detection.
The goals of the project are to develop an integrated materials – technology – product – system concept, demonstrator and prototype for eliminating or minimising the use of chemical batteries, other energy sources, or complex wiring in microsensors/microsystems, increasing the autonomy of sensors, systems and networks, to provide affordable energy technologies with low CO2 emissions and to deliver a portable, autonomous apparatus for water monitoring (detection of nitrates/ nitrides, heavy metals).

Mi a kutatás alapkérdése?
Ebben a részben írja le röviden, hogy mi a kutatás segítségével megválaszolni kívánt probléma, mi a kutatás kiinduló hipotézise, milyen kérdéseket válaszolnak meg a kísérletek.

The main goal of the project is to design and prototype a sustainable autonomous system for nitrates/nitrites and heavy metals monitoring of natural water sources.
Technical objectives: a) Micro (photo)electrochemical sensor design, fabrication and testing; b) Design and fabrication of high efficiency ultra-thin solar cells; c) Power harvesting and storage device integration; d) New materials development for sensors and solar cells (nanowires and nanotubes TiO2, ZnO, TiO2- SnO2, SnO2, CuxS, CZTS, sensing protein molecules, flagellar filaments with large sensing area); e) Investigation with high sensitivity optical method (Grating Coupled Interferometry, GCI), not used before for these purpose, of the deposition of these layers, molecules and their ability to bond the materials to be sensed; f) Optimization of deposition techniques (sol-gel, hydrothermal synthesis, magnetron sputtering, spray pyrolysis, screen printing) and characterization for integration of materials with sensors and solar cells active areas; g) Technology demonstration; h) System (apparatus) prototyping.

Mi a kutatás jelentősége?
Röviden írja le, milyen új perspektívát nyitnak az alapkutatásban az elért eredmények, milyen társadalmi hasznosíthatóságnak teremtik meg a tudományos alapját. Mutassa be, hogy a megpályázott kutatási területen lévő hazai és a nemzetközi versenytársaihoz képest melyek az egyediségei és erősségei a pályázatának!

- Low cost sensors for fast detection of nitrites/ nitrates and heavy metal
The sensing unit will be developed following the same concept of avoiding critical materials or using them at traces level (dopants) and for specific components.
Platinum and doped tin oxide, both deposited with a polymeric membrane will be used as a sensing element (nitrates/nitrites, heavy metals). In, F and Sb will be tested as dopants for the SnO2 layer. Conducting polymers (PANI, PVC and other polymers) will be used as the membrane sensing layer. The auxiliary electrode, reference electrode and working electrode will be integrated on the same silicon chip. The new disposable biosensor for heavy metals detection will use sensing protein molecules, flagellar filaments with large sensing area.
- Enhancement of the material properties by new preparation methods using doping and different morphologies controlled through chemical methods. The use of more synthesis techniques will allow to select the optimum building-blocks, in terms of output (efficiency) and cost-effectiveness.
- High efficiency solar energy harvester
Optimizing the semiconducting layers required for solar cell manufacturing, especially by rigorous control of doping level will be a valid argument for increasing of conversion efficiency. The main threshold properties will be: (a) Interface compatibility of the single-materials in the multi-materials (2D and 3D nano-composites); (b) thermodynamic compatibility (band gaps alignment). The main considerations are applied for (photo)electrochemical sensors.
- Energy autonomous monitoring system (Prototype) - portable, low cost, easy handling, immediate detection

A kutatás összefoglalója, célkitűzései laikusok számára
Ebben a fejezetben írja le a kutatás fő célkitűzéseit alapműveltséggel rendelkező laikusok számára. Ez az összefoglaló a döntéshozók, a média, illetve az érdeklődők tájékoztatása szempontjából különösen fontos az NKFI Hivatal számára.

- Low cost sensors for fast detection of nitrites/ nitrates and heavy metal
The sensing unit will be developed following the same concept of avoiding critical materials or using them at traces level (dopants) and for specific components.
Platinum and doped tin oxide, both deposited with a polymeric membrane will be used as a sensing element (nitrates/nitrites, heavy metals). In, F and Sb will be tested as dopants for the SnO2 layer. Conducting polymers (PANI, PVC and other polymers) will be used as the membrane sensing layer. The auxiliary electrode, reference electrode and working electrode will be integrated on the same silicon chip. The new disposable biosensor for heavy metals detection will use sensing protein molecules, flagellar filaments with large sensing area.
- Enhancement of the material properties by new preparation methods using doping and different morphologies controlled through chemical methods. The use of more synthesis techniques will allow to select the optimum building-blocks, in terms of output (efficiency) and cost-effectiveness.
- High efficiency solar energy harvester
Optimizing the semiconducting layers required for solar cell manufacturing, especially by rigorous control of doping level will be a valid argument for increasing of conversion efficiency. The main threshold properties will be: (a) Interface compatibility of the single-materials in the multi-materials (2D and 3D nano-composites); (b) thermodynamic compatibility (band gaps alignment). The main considerations are applied for (photo)electrochemical sensors.
- Energy autonomous monitoring system (Prototype) - portable, low cost, easy handling, immediate detection
Summary
Summary of the research and its aims for experts
Describe the major aims of the research for experts.

The target is a new energy autonomous system based on micro (photo)electrochemical sensors, for concentration measurement of different ionic species in natural water sources.
It focuses on 3 directions: 1) new materials with high efficiency in solar energy harvesting and fabrication of small ultra-thin solar cells together; 2) new microsensors and materials for detection of nitrites/ nitrates and heavy metals in water; 3) low cost autonomous energy system integration and fabrication.
The microsensors for nitrates/nitrites and heavy metals will be of (photo)electrochemical type. A biosensor based on sensing protein molecules, flagellar filaments with specificity to heavy metals will be integrated.
The studied materials will be SnO2, TiO2 and ZnO. The thin films will be prepared by a broad variety of deposition techniques (sol-gel, spray pyrolysis, magnetron sputtering, hydrothermal synthesis) and will have different morphologies (nanowires, nanotubes, spheres) allowing to select the best sensitivity and selectivity for the sensor. Bacterial flagellar filaments (special protein molecules) will be investigated and engineered as sensitive biolayer for heavy metal detection.
The goals of the project are to develop an integrated materials – technology – product – system concept, demonstrator and prototype for eliminating or minimising the use of chemical batteries, other energy sources, or complex wiring in microsensors/microsystems, increasing the autonomy of sensors, systems and networks, to provide affordable energy technologies with low CO2 emissions and to deliver a portable, autonomous apparatus for water monitoring (detection of nitrates/ nitrides, heavy metals).

What is the major research question?
Describe here briefly the problem to be solved by the research, the starting hypothesis, and the questions addressed by the experiments.

The main goal of the project is to design and prototype a sustainable autonomous system for nitrates/nitrites and heavy metals monitoring of natural water sources.
Technical objectives: a) Micro (photo)electrochemical sensor design, fabrication and testing; b) Design and fabrication of high efficiency ultra-thin solar cells; c) Power harvesting and storage device integration; d) New materials development for sensors and solar cells (nanowires and nanotubes TiO2, ZnO, TiO2- SnO2, SnO2, CuxS, CZTS, sensing protein molecules, flagellar filaments with large sensing area); e) Investigation with high sensitivity optical method (Grating Coupled Interferometry, GCI), not used before for these purpose, of the deposition of these layers, molecules and their ability to bond the materials to be sensed; f) Optimization of deposition techniques (sol-gel, hydrothermal synthesis, magnetron sputtering, spray pyrolysis, screen printing) and characterization for integration of materials with sensors and solar cells active areas; g) Technology demonstration; h) System (apparatus) prototyping.

What is the significance of the research?
Describe the new perspectives opened by the results achieved, including the scientific basics of potential societal applications. Please describe the unique strengths of your proposal in comparison to your domestic and international competitors in the given field.

- Low cost sensors for fast detection of nitrites/ nitrates and heavy metal
The sensing unit will be developed following the same concept of avoiding critical materials or using them at traces level (dopants) and for specific components.
Platinum and doped tin oxide, both deposited with a polymeric membrane will be used as a sensing element (nitrates/nitrites, heavy metals). In, F and Sb will be tested as dopants for the SnO2 layer. Conducting polymers (PANI, PVC and other polymers) will be used as the membrane sensing layer. The auxiliary electrode, reference electrode and working electrode will be integrated on the same silicon chip. The new disposable biosensor for heavy metals detection will use sensing protein molecules, flagellar filaments with large sensing area.
- Enhancement of the material properties by new preparation methods using doping and different morphologies controlled through chemical methods. The use of more synthesis techniques will allow to select the optimum building-blocks, in terms of output (efficiency) and cost-effectiveness.
- High efficiency solar energy harvester
Optimizing the semiconducting layers required for solar cell manufacturing, especially by rigorous control of doping level will be a valid argument for increasing of conversion efficiency. The main threshold properties will be: (a) Interface compatibility of the single-materials in the multi-materials (2D and 3D nano-composites); (b) thermodynamic compatibility (band gaps alignment). The main considerations are applied for (photo)electrochemical sensors.
- Energy autonomous monitoring system (Prototype) - portable, low cost, easy handling, immediate detection

Summary and aims of the research for the public
Describe here the major aims of the research for an audience with average background information. This summary is especially important for NRDI Office in order to inform decision-makers, media, and others.

- Low cost sensors for fast detection of nitrites/ nitrates and heavy metal
The sensing unit will be developed following the same concept of avoiding critical materials or using them at traces level (dopants) and for specific components.
Platinum and doped tin oxide, both deposited with a polymeric membrane will be used as a sensing element (nitrates/nitrites, heavy metals). In, F and Sb will be tested as dopants for the SnO2 layer. Conducting polymers (PANI, PVC and other polymers) will be used as the membrane sensing layer. The auxiliary electrode, reference electrode and working electrode will be integrated on the same silicon chip. The new disposable biosensor for heavy metals detection will use sensing protein molecules, flagellar filaments with large sensing area.
- Enhancement of the material properties by new preparation methods using doping and different morphologies controlled through chemical methods. The use of more synthesis techniques will allow to select the optimum building-blocks, in terms of output (efficiency) and cost-effectiveness.
- High efficiency solar energy harvester
Optimizing the semiconducting layers required for solar cell manufacturing, especially by rigorous control of doping level will be a valid argument for increasing of conversion efficiency. The main threshold properties will be: (a) Interface compatibility of the single-materials in the multi-materials (2D and 3D nano-composites); (b) thermodynamic compatibility (band gaps alignment). The main considerations are applied for (photo)electrochemical sensors.
- Energy autonomous monitoring system (Prototype) - portable, low cost, easy handling, immediate detection





 

Events of the project

 
2017-03-16 14:24:07
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