Ultrafast quantum dynamcs: Classical and nonclassical description  Page description

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Details of project

  
Identifier
128396
Type K
Principal investigator Vibók, Ágnes
Title in Hungarian Ultragyors kvantumdinamika: Klasszikus és nem klasszikus leirás
Title in English Ultrafast quantum dynamcs: Classical and nonclassical description
Keywords in Hungarian kónikus kereszteződés; intenzív elektromágneses tér; ultragyors elektron és magdinamika; üregrezonátor;
Keywords in English conical intersections; strong electromagnetic field; ultrafast electron and nuclear dynamics; cavity;
Discipline
Physics (Council of Physical Sciences)100 %
Ortelius classification: Molecular physics
Panel Physics 1
Department or equivalent Department of Theoretical Physics (University of Debrecen)
Participants Badankó, Péter
Csehi, András
Fábri, Csaba
Halász, Gábor
Szabó, Krisztián
Starting date 2018-10-01
Closing date 2023-12-31
Funding (in million HUF) 17.032
FTE (full time equivalent) 12.83
state running project





 

Final report

  
Results in Hungarian
A fényindukált nemadiabatikus hatás szabályozható módon csatolja a molekulák különböző elektronállapotait, és a térintenzitástól függően ez a csatolás erős is lehet a fényindukált kónikus kereszteződések (LICI) közelében. A LICI jelenléte számos statikus és dinamikus nemdiabatikus jelenség forrása. A fény-indukált gyors, nemadiabatikus dinamikát és interferenciahatásokat vizsgáltuk számos kétatomos molekuláris rendszer esetében. Emellett néhány két- és többatomos molekula fény-öltöztetett forgási-rezgési spektruma is tanulmányozásra került. Fókuszáltunk a kvantumfény által kiváltott nemdiabatikus jelenségekre is. Alternatívájaként a molekulák intenzív lézerterekkel történő kölcsönhatásainak, erős fény-anyag csatolás érhető el a molekulák mikro méretű optikai vagy plazmonikus üreg-rezonátorokba történő zárásával is. Az ilyen rendszereket általában fény-öltöztetett vagy polariton állapotokkal írják le, amelyek a teljes „molekula + sugárzási tér” rendszer sajátállapotai. Ebben a megközelítésben számos két- és többatomos rendszer dinamikai, spektroszkópiai és topológiai tulajdonságait vizsgáltuk. Különösen fontos az az általános megállapításunk, hogy a Born-Oppenheimer közelítés érvényét veszítheti kvantum-fény által indukált kónikus kereszteződés hatására, s ez az effektus már többatomos molekulák kétdimenziós modelljében is megjelenik.
Results in English
Light-induced nonadiabaticity couples in a controllable way the different electronic states of the molecule and depending on the field intensity this coupling can be strong in the vicinity of the light-induced conical intersections (LICIs). The presence of a LICI provides a source for numerous statical and dynamical nonadiabatic phenomena. Concerning dynamics and interference effects due to LICIs,we have studied the impact of the LICI on the dissociation dynamics of several diatomic systems. Moreover, we have also investigated the dressed state rovibronic spectra of several diatomic and polyatomic molecules. We have also concentrated on the subject of quantum light-induced nonadiabatic phenomena. It is an alternative to interactions of molecules with intense laser fields, strong light−matter coupling can also be achieved by the confinement of molecules in microscale optical or plasmonic nano-cavities. Such systems are usually described in terms of field-dressed or polariton states, which are the eigenstates of the full “molecule + radiation field” system. In this framework, we have investigated several dynamical, spectroscopic and topological properties of diatomic and polyatomic systems. Of particular importance is our general finding that the Born-Oppenheimer approximation fails in the presence of a LICI which is already present in the two dimensional model.
Full text https://www.otka-palyazat.hu/download.php?type=zarobeszamolo&projektid=128396
Decision
Yes





 

List of publications

  
Csehi András, Kowalewski Markus, Halász Gábor J, Vibók Ágnes: Ultrafast dynamics in the vicinity of quantum light-induced conical intersections, NEW JOURNAL OF PHYSICS 21: (9) p. 093040., 2019
Tóth A., Csehi A., Halász G. J., Vibók Á.: Photodissociation dynamics of the LiF molecule: Two- and three-state descriptions, PHYSICAL REVIEW A 99: (4) 043424, 2019
Badanko Peter, Halasz Gabor J., Cederbaum Lorenz S., Vibok Agnes, Csehi Andras: Communication: Substantial impact of the orientation of transition dipole moments on the dynamics of diatomics in laser fields, JOURNAL OF CHEMICAL PHYSICS 149: (18) 181101, 2018
Szidarovszky Tamás, Halász Gábor J., Császár Attila G., Cederbaum Lorenz S., Vibók Ágnes: Conical Intersections Induced by Quantum Light: Field-Dressed Spectra from the Weak to the Ultrastrong Coupling Regimes, JOURNAL OF PHYSICAL CHEMISTRY LETTERS 9: (21) pp. 6215-6223., 2018
Csehi Andras, Badanko Peter, Halasz Gabor J., Vibok Agnes, Lasorne Benjamin: On the preservation of coherence in the electronic wavepacket of a neutral and rigid polyatomic molecule, JOURNAL OF PHYSICS B: ATOMIC MOLECULAR AND OPTICAL PHYSICS 53: (18) 184005, 2020
Fabri Csaba, Lasorne Benjamin, Halasz Gabor J., Cederbaum Lorenz S., Vibok Agnes: Striking Generic Impact of Light-Induced Non-Adiabaticity in Polyatomic Molecules, JOURNAL OF PHYSICAL CHEMISTRY LETTERS 11: (13) pp. 5324-5329., 2020
Pawlak Mariusz, Szidarovszky Tamás, Halász Gábor J., Vibók Ágnes: Robust field-dressed spectra of diatomics in an optical lattice, PHYSICAL CHEMISTRY CHEMICAL PHYSICS 22: pp. 3715-3723., 2020
Tóth A., Csehi A., Halász G. J., Vibók Á.: Control of photodissociation with the dynamic Stark effect induced by THz pulses, Physical Review Research 2: (1) 013338, 2020
Csehi András, Vibók Ágnes, Halász Gábor J., Kowalewski Markus: Quantum control with quantum light of molecular nonadiabaticity, PHYSICAL REVIEW A 100: (5) 053421, 2019
Badanko Peter, Umarov Otabek, Fabri Csaba, Halasz Gabor J., Vibok Agnes: Topological aspects of cavity-induced degeneracies in polyatomic molecules, INTERNATIONAL JOURNAL OF QUANTUM CHEMISTRY 2021: e26750, 2021
Fábri Csaba, Halász Gábor J., Cederbaum Lorenz S., Vibók Ágnes: Born–Oppenheimer approximation in optical cavities: from success to breakdown, CHEMICAL SCIENCE 12: (4) pp. 1251-1258., 2021
Fábri Csaba, Halász Gábor J., Cederbaum Lorenz S., Vibók Ágnes: Signatures of light-induced nonadiabaticity in the field-dressed vibronic spectrum of formaldehyde, JOURNAL OF CHEMICAL PHYSICS 154: (12) 124308, 2021
Szidarovszky Tamás, Badankó Péter, Halász Gábor J., Vibók Ágnes: Nonadiabatic phenomena in molecular vibrational polaritons, JOURNAL OF CHEMICAL PHYSICS 154: (6) 064305, 2021
Fábri Csaba, Lasorne Benjamin, Halász Gábor J., Cederbaum Lorenz S., Vibók Ágnes: Quantum light-induced nonadiabatic phenomena in the absorption spectrum of formaldehyde: Full- and reduced-dimensionality studies, JOURNAL OF CHEMICAL PHYSICS 153: (23) 234302, 2020
Szidarovszky Tamás, Halász Gábor J., Vibok Agnes: Three-player polaritons: nonadiabatic fingerprints in an entangled atom-molecule-photon system, NEW JOURNAL OF PHYSICS 22: (5) 053001, 2020
Csaba Fábri, Halász Gábor J., Vibók Ágnes: Probing Light-Induced Conical Intersections by Monitoring Multidimensional Polaritonic Surfaces, JOURNAL OF PHYSICAL CHEMISTRY LETTERS 13: (5) pp. 1172-1179., 2022
Csehi András, Vendrell Oriol, Halász Gábor J, Vibók Ágnes: Competition between collective and individual conical intersection dynamics in an optical cavity, NEW JOURNAL OF PHYSICS 24: (7) 073022, 2022
Gabor Halász, Tamás Szidarovszky, Agnes Vibok: On the line shape of the total rovibronic absorption in laser-dressed diatomic molecules, INTERNATIONAL JOURNAL OF QUANTUM CHEMISTRY 122: (7) e26868, 2022
Fabri Csaba, Halász Gábor J., Cederbaum Lorenz S, Vibok Agnes: Radiative emission of polaritons controlled by light-induced geometric phase, CHEMICAL COMMUNICATIONS 58: (90) pp. 12612-12615., 2022
Szidarovszky Tamás, Halász Gábor J., Császár Attila G., Cederbaum Lorenz S., Vibók Ágnes: Conical Intersections Induced by Quantum Light: Field-Dressed Spectra from the Weak to the Ultrastrong Coupling Regimes, JOURNAL OF PHYSICAL CHEMISTRY LETTERS 9: (21) pp. 6215-6223., 2018
Badanko Peter, Halasz Gabor J., Cederbaum Lorenz S., Vibok Agnes, Csehi Andras: Communication: Substantial impact of the orientation of transition dipole moments on the dynamics of diatomics in laser fields, JOURNAL OF CHEMICAL PHYSICS 149: (18) 181101, 2018
Tóth A., Csehi A., Halász G. J., Vibók Á.: Photodissociation dynamics of the LiF molecule: Two- and three-state descriptions, PHYSICAL REVIEW A 99: (4) 043424, 2019
Csehi András, Kowalewski Markus, Halász Gábor J, Vibók Ágnes: Ultrafast dynamics in the vicinity of quantum light-induced conical intersections, NEW JOURNAL OF PHYSICS 21: (9) p. 093040., 2019
Csehi András, Vibók Ágnes, Halász Gábor J., Kowalewski Markus: Quantum control with quantum light of molecular nonadiabaticity, PHYSICAL REVIEW A 100: (5) 053421, 2019
Pawlak Mariusz, Szidarovszky Tamás, Halász Gábor J., Vibók Ágnes: Robust field-dressed spectra of diatomics in an optical lattice, PHYSICAL CHEMISTRY CHEMICAL PHYSICS 22: pp. 3715-3723., 2020
Tóth A., Csehi A., Halász G. J., Vibók Á.: Control of photodissociation with the dynamic Stark effect induced by THz pulses, Physical Review Research 2: (1) 013338, 2020
Fabri Csaba, Lasorne Benjamin, Halasz Gabor J., Cederbaum Lorenz S., Vibok Agnes: Striking Generic Impact of Light-Induced Non-Adiabaticity in Polyatomic Molecules, JOURNAL OF PHYSICAL CHEMISTRY LETTERS 11: (13) pp. 5324-5329., 2020
Csehi Andras, Badanko Peter, Halasz Gabor J., Vibok Agnes, Lasorne Benjamin: On the preservation of coherence in the electronic wavepacket of a neutral and rigid polyatomic molecule, JOURNAL OF PHYSICS B: ATOMIC MOLECULAR AND OPTICAL PHYSICS 53: (18) 184005, 2020
Szidarovszky Tamás, Halász Gábor J., Vibok Agnes: Three-player polaritons: nonadiabatic fingerprints in an entangled atom-molecule-photon system, NEW JOURNAL OF PHYSICS 22: (5) 053001, 2020
Fábri Csaba, Halász Gábor J., Cederbaum Lorenz S., Vibók Ágnes: Born–Oppenheimer approximation in optical cavities: from success to breakdown, CHEMICAL SCIENCE 12: (4) pp. 1251-1258., 2021
Fábri Csaba, Lasorne Benjamin, Halász Gábor J., Cederbaum Lorenz S., Vibók Ágnes: Quantum light-induced nonadiabatic phenomena in the absorption spectrum of formaldehyde: Full- and reduced-dimensionality studies, JOURNAL OF CHEMICAL PHYSICS 153: (23) 234302, 2020
Szidarovszky Tamás, Badankó Péter, Halász Gábor J., Vibók Ágnes: Nonadiabatic phenomena in molecular vibrational polaritons, JOURNAL OF CHEMICAL PHYSICS 154: (6) 064305, 2021
Fábri Csaba, Halász Gábor J., Cederbaum Lorenz S., Vibók Ágnes: Signatures of light-induced nonadiabaticity in the field-dressed vibronic spectrum of formaldehyde, JOURNAL OF CHEMICAL PHYSICS 154: (12) 124308, 2021
Badanko Peter, Umarov Otabek, Fabri Csaba, Halasz Gabor J., Vibok Agnes: Topological aspects of cavity-induced degeneracies in polyatomic molecules, INTERNATIONAL JOURNAL OF QUANTUM CHEMISTRY 2021: e26750, 2022
Gabor Halász, Tamás Szidarovszky, Agnes Vibok: On the line shape of the total rovibronic absorption in laser-dressed diatomic molecules, INTERNATIONAL JOURNAL OF QUANTUM CHEMISTRY 122: (7) e26868, 2022
Csaba Fábri, Halász Gábor J., Vibók Ágnes: Probing Light-Induced Conical Intersections by Monitoring Multidimensional Polaritonic Surfaces, JOURNAL OF PHYSICAL CHEMISTRY LETTERS 13: (5) pp. 1172-1179., 2022
Csehi András, Vendrell Oriol, Halász Gábor J, Vibók Ágnes: Competition between collective and individual conical intersection dynamics in an optical cavity, NEW JOURNAL OF PHYSICS 24: (7) 073022, 2022
Fabri Csaba, Halász Gábor J., Cederbaum Lorenz S, Vibok Agnes: Radiative emission of polaritons controlled by light-induced geometric phase, CHEMICAL COMMUNICATIONS 58: (90) pp. 12612-12615., 2022
Attila Tóth, Sándor Borbély and András Csehi: Dynamic interference in below-threshold ionization, Phys. Rev. A 108, L061101, 2023




 

Events of the project

  
2022-11-23 10:25:43
Résztvevők változása
2022-01-18 12:54:06
Résztvevők változása



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